Carboxylic Acid Chloride Reactions

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Note that products are shown after neutralization, and neutralization of products is NOT shown here for simplicity. Exception: acid-base reactions.


Anhydrides react in essentially the same way but yield one mole of the carboxylic acid instead of HCl as product. In addition, sulfonic, sulfuric, phosphoric, and other acid chlorides and anhydrides undergo analogous reactions to form esters, amides, etc.

Addition / Elimination Reactions

+ HCl
Mechanism!
Reference Schmid 16.5
To other syntheses of acids
+ HCl
Mechanism!
Reference Schmid 16.5
To other syntheses of esters
+ HCl
Reference Schmid 16.5
+
Mechanism!
Reference Schmid 16.5
+ HCl
Mechanism!
Reference Schmid 16.5
To other syntheses of amides
+ HCl
Mechanism!
Reference Schmid 16.5
To other syntheses of amides

Addition / Reduction


Other reagents: NaBH4
Reference Schmid 16.12
To syntheses of alcohols

Reference Schmid 16.14, A
To: Syntheses of aldehydes

Reference Schmid 16.13
To: Synthesis of alcohols

Reference Schmid 16.14, B
To: Synthesis of ketones

Synthesis of Acid Chlorides

+ SO2 + HCl
Reference: Schmid 16.5
To main graphical reactions menu